It’s one of four matches to take place this week and to be shown live on BT Sport with highlights on ITV.
The Gunners hope it will be a case of third time lucky as the Premier League side have lost their two previous two-legged knockout ties against Barcelona, who also won in England at this stage of the competition in 2014 and 2015.
Arsenal did came from behind to beat Barcelona 2-1 when the teams last met in London in the 2010/11 round of 16, with Robin van Persie and Andrey Arshavin overturning David Villa’s first-half goal.
Elsewhere, Dynamo Kiev take on Manchester City at the Olympic Stadium, PSV Eindhoven face Atletico Madrid at the Philips Stadion, while Bayern Munich travelled to face Juventus in Turin.
Arsenal v Barcelona is live on BT Sport Europe from 7.00pm with live streaming on BTSport.com and via the BT Sport App. Kick-off 7.45pm.
Arsenal v Barcelona
Tues 23 Feb – BT Sport Europe, 7.00pm – ko 7.45pm
Juventus v Bayern Munich
Tues 23 Feb – BT Sport 2, 7.00pm – ko 7.45pm
Dynamo Kiev v Manchester City
Wed 24 Feb – BT Sport Europe, 7.00pm – ko 7.45pm
PSV Eindhoven v Atletico Madrid
Wed 24 Feb – BT Sport 2, 7.00pm – ko 7.45pm
UEFA Champions League Highlights
Wed 24 Feb – ITV, 11.05pm
The running order for this week’s edition of Match of the Day is as follows: 1. Manchester City v Tottenham Hotspur; 2. Norwich City v Newcastle United; 3. Southampton v Liverpool; 4. Arsenal v Burnley. 5. Aston Villa v Bournemouth;… Read more
BT Sport will broadcast the Premier League clash between Arsenal and Burnley this afternoon. It will be the first of five league matches to be shown on live TV this weekend. The Clarets head to the Emirates Stadium full of… Read more
The Champions League and Europa League holders face-off this evening as Liverpool meet Chelsea in the UEFA Super Cup final. This is the first all-English UEFA Super Cup, though it is the fifth time in six seasons domestic rivals have… Read more